Unknown

Dataset Information

0

Near-infrared cavity ring-down spectroscopy measurements of nitrous oxide in the (4200)←(0000) and (5000)←(0000) bands.


ABSTRACT: Using frequency-agile rapid scanning cavity ring-down spectroscopy, we measured line intensities and line shape parameters of 14N2 16O in air in the (4200)←(0000) and (5000)←(0000) bands near 1.6 µm. The absorption spectra were modeled with multi-spectrum fits of Voigt and speed-dependent Voigt profiles. The measured line intensities and air-broadening parameters exhibit deviations of several percent relative to values provided in HITRAN 2016. Our measured intensities for these two bands have relative combined standard uncertainties of ∼1% which is approximately five times smaller than literature values. Comparison of the present air-broadening and speed-dependent broadening parameters to experimental literature values for other rotation-vibration bands of N2O indicates significant differences in magnitude and J-dependence. For applications requiring high spectral fidelity, these results suggest that the assumption of band-independent line shape parameters is not appropriate.

SUBMITTER: Adkins EM 

PROVIDER: S-EPMC9706648 | biostudies-literature | 2021 Mar

REPOSITORIES: biostudies-literature

altmetric image

Publications

Near-infrared cavity ring-down spectroscopy measurements of nitrous oxide in the (4200)←(0000) and (5000)←(0000) bands.

Adkins Erin M EM   Long David A DA   Fleisher Adam J AJ   Hodges Joseph T JT  

Journal of quantitative spectroscopy & radiative transfer 20210301


Using frequency-agile rapid scanning cavity ring-down spectroscopy, we measured line intensities and line shape parameters of <sup>14</sup>N<sub>2</sub> <sup>16</sup>O in air in the (4200)←(0000) and (5000)←(0000) bands near 1.6 <i>µ</i>m. The absorption spectra were modeled with multi-spectrum fits of Voigt and speed-dependent Voigt profiles. The measured line intensities and air-broadening parameters exhibit deviations of several percent relative to values provided in HITRAN 2016. Our measured  ...[more]

Similar Datasets

| S-EPMC5257295 | biostudies-literature
| S-EPMC11808761 | biostudies-literature
| S-EPMC11656205 | biostudies-literature
| S-EPMC4519009 | biostudies-literature
| S-EPMC9082503 | biostudies-literature
| S-EPMC9194856 | biostudies-literature
| S-EPMC5040641 | biostudies-literature
| S-EPMC4778072 | biostudies-other
| S-EPMC8655739 | biostudies-literature
| S-EPMC9123425 | biostudies-literature