Breaking Rotational Symmetry in Supertwisted WS₂ Spirals via Moire Magnification of Intrinsic Heterostrain.

ABSTRACT: Twisted stacking of van der Waals materials with moiré superlattices offers a new way to tailor their physical properties via engineering of the crystal symmetry. Unlike well-studied twisted bilayers, little is known about the overall symmetry and symmetry-driven physical properties of continuously supertwisted multilayer structures. Here, using polarization-resolved second harmonic generation (SHG) microscopy, we report threefold (C₃) rotational symmetry breaking in supertwisted WS₂ spirals grown on non-Euclidean surfaces, contrasting the intact symmetry of individual monolayers. This symmetry breaking is attributed to a geometrical magnifying effect in which small relative strain between adjacent twisted layers (heterostrain), verified by Raman spectroscopy and multiphysics simulations, generates significant distortion in the moiré pattern. Density-functional theory calculations can explain the C₃ symmetry breaking and unusual SHG response by the interlayer wave function coupling. These findings thus pave the way for further developments in the so-called "3D twistronics".

SUBMITTER: Ci P 

PROVIDER: S-EPMC9706673 | biostudies-literature | 2022 Nov

REPOSITORIES: biostudies-literature