Ontology highlight
ABSTRACT:
SUBMITTER: Galetto FZ
PROVIDER: S-EPMC9710311 | biostudies-literature | 2022 Nov
REPOSITORIES: biostudies-literature
Galetto Fábio Z FZ da Silva Cleiton C Beche Ricardo I M RIM Balaguez Renata A RA Franco Marcelo S MS de Assis Francisco F FF Frizon Tiago E A TEA Su Xiao X
RSC advances 20221130 53
We report herein the synthesis of primary and secondary β-chalcogen amines through the regioselective ring-opening reaction of non-activated 2-oxazolidinones promoted by <i>in situ</i> generated chalcogenolate anions. The developed one-step protocol enabled the preparation of β-selenoamines, β-telluroamines and β-thioamines with appreciable structural diversity and in yields of up to 95%. ...[more]