Unknown

Dataset Information

0

Decarboxylative ring-opening of 2-oxazolidinones: a facile and modular synthesis of β-chalcogen amines.


ABSTRACT: We report herein the synthesis of primary and secondary β-chalcogen amines through the regioselective ring-opening reaction of non-activated 2-oxazolidinones promoted by in situ generated chalcogenolate anions. The developed one-step protocol enabled the preparation of β-selenoamines, β-telluroamines and β-thioamines with appreciable structural diversity and in yields of up to 95%.

SUBMITTER: Galetto FZ 

PROVIDER: S-EPMC9710311 | biostudies-literature | 2022 Nov

REPOSITORIES: biostudies-literature

altmetric image

Publications

Decarboxylative ring-opening of 2-oxazolidinones: a facile and modular synthesis of β-chalcogen amines.

Galetto Fábio Z FZ   da Silva Cleiton C   Beche Ricardo I M RIM   Balaguez Renata A RA   Franco Marcelo S MS   de Assis Francisco F FF   Frizon Tiago E A TEA   Su Xiao X  

RSC advances 20221130 53


We report herein the synthesis of primary and secondary β-chalcogen amines through the regioselective ring-opening reaction of non-activated 2-oxazolidinones promoted by <i>in situ</i> generated chalcogenolate anions. The developed one-step protocol enabled the preparation of β-selenoamines, β-telluroamines and β-thioamines with appreciable structural diversity and in yields of up to 95%. ...[more]

Similar Datasets

| S-EPMC11681771 | biostudies-literature
| S-EPMC7408245 | biostudies-literature
| S-EPMC4930112 | biostudies-literature
| S-EPMC7506026 | biostudies-literature
| S-EPMC5839468 | biostudies-literature
| S-EPMC2583445 | biostudies-literature
| S-EPMC5682613 | biostudies-literature
| S-EPMC6542561 | biostudies-literature
| S-EPMC6151605 | biostudies-literature
| S-EPMC11375436 | biostudies-literature