Ni-Doped CuO Nanoarrays Activate Urea Adsorption and Stabilizes Reaction Intermediates to Achieve High-Performance Urea Oxidation Catalysts.

ABSTRACT: Urea oxidation reaction (UOR) with a low equilibrium potential offers a promising route to replace the oxygen evolution reaction for energy-saving hydrogen generation. However, the overpotential of the UOR is still high due to the complicated 6e^- transfer process and adsorption/desorption of intermediate products. Herein, utilizing a cation exchange strategy, Ni-doped CuO nanoarrays grown on 3D Cu foam are synthesized. Notably, Ni-CuO NAs/CF requires a low potential of 1.366 V versus a reversible hydrogen electrode to drive a current density of 100 mA cm^-2 , outperforming various benchmark electrocatalysts and maintaining robust stability in alkaline media. Theoretical and experimental studies reveal that Ni as the driving force center can effectively enhance the urea

SUBMITTER: Sun H 

PROVIDER: S-EPMC9731696 | biostudies-literature | 2022 Dec

REPOSITORIES: biostudies-literature