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Synthesis, Structure, and Characterization of 4,4'-(Anthracene-9,10-diylbis(ethyne-2,1-diyl))bis(1-methyl-1-pyridinium) Bismuth Iodide (C₃₀H₂₂N₂)₃Bi₄I₁₈, an Air, Water, and Thermally Stable 0D Hybrid Perovskite with High Photoluminescence Efficiency.

ABSTRACT: 4,4'-(Anthracene-9,10-diylbis(ethyne-2,1-diyl))bis(1-methyl-1-pyridinium) bismuth iodide (C₃₀H₂₂N₂)₃Bi₄I₁₈ (AEPyBiI) was obtained as a black powder by a very simple route by mixing an acetone solution of BiI₃ and an aqueous solution of C₃₀H₂₂N₂I₂. This novel perovskite is air and water stable and displays a remarkable thermal stability up to nearly 300 °C. The highly conjugated cation C₃₀H₂₂N₂ ²⁺ is hydrolytically stable, being nitrogen atoms quaternarized, and this accounts for the insensitivity of the perovskite toward water and atmospheric oxygen under ambient conditions. The cation in aqueous solution is highly fluorescent

SUBMITTER: Romagnoli L

PROVIDER: S-EPMC9732820 | biostudies-literature | 2022 Dec

REPOSITORIES: biostudies-literature

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Dataset Information

Synthesis, Structure, and Characterization of 4,4'-(Anthracene-9,10-diylbis(ethyne-2,1-diyl))bis(1-methyl-1-pyridinium) Bismuth Iodide (C₃₀H₂₂N₂)₃Bi₄I₁₈, an Air, Water, and Thermally Stable 0D Hybrid Perovskite with High Photoluminescence Efficiency.

OmicsDI is part of the ELIXIR infrastructure

Tweets

Dataset Information

Synthesis, Structure, and Characterization of 4,4'-(Anthracene-9,10-diylbis(ethyne-2,1-diyl))bis(1-methyl-1-pyridinium) Bismuth Iodide (C30H22N2)3Bi4I18, an Air, Water, and Thermally Stable 0D Hybrid Perovskite with High Photoluminescence Efficiency.

OmicsDI is part of the ELIXIR infrastructure

Tweets

Synthesis, Structure, and Characterization of 4,4'-(Anthracene-9,10-diylbis(ethyne-2,1-diyl))bis(1-methyl-1-pyridinium) Bismuth Iodide (C₃₀H₂₂N₂)₃Bi₄I₁₈, an Air, Water, and Thermally Stable 0D Hybrid Perovskite with High Photoluminescence Efficiency.