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Synthesis and the Crystal Structure of a New Chiral 1D Metal-Organic Coordination Polymer Based on L-Prolineamide-Substituted Diarylacetylenedicarboxylic Acid Derivative.
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ABSTRACT:
SUBMITTER: Veselovsky VV
PROVIDER: S-EPMC9738848 | biostudies-literature | 2022 Nov
REPOSITORIES: biostudies-literature
Publications
Synthesis and the Crystal Structure of a New Chiral 1D Metal-Organic Coordination Polymer Based on L-Prolineamide-Substituted Diarylacetylenedicarboxylic Acid Derivative.
Molecules (Basel, Switzerland) 20221130 23
The new homochiral 1D metal-organic coordination polymer [<b>Cu<sub>2</sub>(EDPB)•H<sub>2</sub>O]<sub>n</sub></b> was synthesized starting from the original 3,3'-ethyne-1,2-diylbis[6-(L-prolylamino)benzoic acid] (H<sub>4</sub>EDPB). The unique crystal structure of the new compound was established by powder X-ray diffraction. The [<b>Cu<sub>2</sub>(EDPB)•H<sub>2</sub>O]<sub>n</sub></b> system shows catalytic activity and enantioselectivity in a Henry reaction of <i>p</i>-nitrobenzaldehyde with ni ...[more]