Valence Localization in Alkyne and Alkene Adducts of Synthetic [Fe₄S₄]⁺ Clusters.

ABSTRACT: Reported herein are alkyne and alkene adducts of synthetic [Fe₄S₄]⁺ clusters that model intermediates and inhibitor-bound states in enzymes involved in isoprenoid biosynthesis. Treatment of the N-heterocyclic carbene-ligated cluster [(IMes)₃Fe₄S₄(OEt₂)][BAr^F₄] (IMes = 1,3-dimesitylimidazol-2-ylidene; [BAr^F₄]^- = tetrakis(3,5-bis(trifluoromethyl)phenyl)borate) with phenylacetylene (PhCCH) or cis-cyclooctene (COE) results in displacement of the Et₂O ligand to yield the corresponding π complexes, [(IMes)₃Fe₄S₄(PhCCH)][BAr^F₄] and [(IMes)₃Fe₄S₄(COE)][BAr<

SUBMITTER: Brown AC 

PROVIDER: S-EPMC9751231 | biostudies-literature | 2023 Feb

REPOSITORIES: biostudies-literature