Anisotropic Hyperfine Interaction of Surface-Adsorbed Single Atoms.

ABSTRACT: Hyperfine interactions have been widely used in material science, organic chemistry, and structural biology as a sensitive probe to local chemical environments. However, traditional ensemble measurements of hyperfine interactions average over a macroscopic number of spins with different geometrical locations and nuclear isotopes. Here, we use a scanning tunneling microscope (STM) combined with electron spin resonance (ESR) to measure hyperfine spectra of hydrogenated-Ti on MgO/Ag(100) at low-symmetry binding sites and thereby determine the isotropic and anisotropic hyperfine interactions at the single-atom level. Combining vector-field ESR spectroscopy with STM-based atom manipulation, we characterize the full hyperfine tensors of ⁴⁷Ti and ⁴⁹Ti and identify significan

SUBMITTER: Kim J 

PROVIDER: S-EPMC9756343 | biostudies-literature | 2022 Nov

REPOSITORIES: biostudies-literature