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Modeling of the stability of water-based graphite dispersions using polyvinylpyrrolidone on the basis of the DLVO theory.

ABSTRACT: The applications of graphite nanoparticle dispersions emerge due to the increasing importance of printed electronics and microelectronics, lithium-ion batteries, and supercapacitors. Promising technologies are inkjet printing processes, which are significantly influenced by the dispersion stability. Achieving stability is particularly challenging for nanoparticle dispersions due to the strong attractive forces emanating from the large particle surfaces. Despite the significance attributed to stability, it is predominantly investigated empirically. The only existing model to mathematically describe interparticle forces is given by the DLVO theory. This paper uses the extended DLVO theory to model the stability of aqueous graphite dispersions. Furthermore, the influences arising from an electrosterically stabilizing dispersant, in this case polyvinylpyrrolidone (PVP), were incorporated in the model. Experimentally data obtained from sedimentation analyses concur with the DLVO theory prediction. Due to the universality of the model, it is expected to be applicable to different material and dispersant systems.

SUBMITTER: Kolb CG

PROVIDER: S-EPMC9763744 | biostudies-literature | 2022 Dec

REPOSITORIES: biostudies-literature

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Modeling of the stability of water-based graphite dispersions using polyvinylpyrrolidone on the basis of the DLVO theory.

Kolb Cara Greta CG Lehmann Maja M Kulmer Dominik D Zaeh Michael Friedrich MF

Heliyon 20221205 12

The applications of graphite nanoparticle dispersions emerge due to the increasing importance of printed electronics and microelectronics, lithium-ion batteries, and supercapacitors. Promising technologies are inkjet printing processes, which are significantly influenced by the dispersion stability. Achieving stability is particularly challenging for nanoparticle dispersions due to the strong attractive forces emanating from the large particle surfaces. Despite the significance attributed to sta ...[more]

PMID: 36561674

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Project description:In a spray drying operation, a two-fluid nozzle (2FN) with a single channel is commonly used for atomizing the feed solution. However, the less commonly used three-fluid nozzle (3FN) has two separate channels, which allow spray drying of materials in two incompatible solution systems. Although amorphous solid dispersions (ASDs) prepared using a 3FN have been reported to deliver comparable drug dissolution performance relative to those prepared using a 2FN, few studies have systematically examined the effect of 3FN on the physical stability. Therefore, the goal of this work is to systematically study the physical stability of ASDs that are spray-dried using a 3FN compared to those prepared using the traditional 2FN. For the 2FN, a single solution of naproxen and polyvinylpyrrolidone (PVP) was prepared in a mixture of acetone and water at a 1:1 volume ratio because 2FN allows for only one solution inlet. For the 3FN, naproxen and PVP were dissolved individually in acetone and water, respectively, because 3FN allows simultaneous entry of two solutions. Upon storage of the formulated ASDs at different humidity levels (25%, 55% and 75% RH), naproxen crystallized more quickly from the 3FN ASDs as compared with the 2FN ASDs. 3FN ASDs crystallized after 5 days of storage at all conditions, whereas 2FN ASDs did not crystallize even at 55% RH for two months. This relatively higher crystallization tendency of 3FN ASDs was attributed to the inhomogeneity of drug and polymers as identified by the solid-state Nuclear Magnetic Resonance findings, specifically due to poor mixing of water- and acetone-based solutions at the 3FN nozzle. When only acetone was used as a solvent to prepare drug-polymer solutions for 3FN, the formulated ASD was found to be stable for >3 months of storage (at 75% RH), which suggests that instability of the 3FN ASD was due to the insufficient mixing of water and acetone solutions. This study provides insights into the effects of solvent and nozzle choices on the physical stability of spray-dried ASDs.

Project description:The aim of this work was to demonstrate an optimization methodology to reliably obtain stable macrodispersions (i.e., for ≥24 h) of carbon nanotubes in water using sonication. Response surface methodology (RSM) was utilized to assess and optimize the sonication parameters for the process. The studied input parameters were (i) sonication time (duration), (ii) amplitude (of vibration), and (iii) pulse-on/off (duration) of the sonicator. The analyzed responses were mean diameter and size distribution of multiwalled carbon nanotube (MWNT) aggregates in water, which were measured by the dynamic light scattering technique. A semiempirical model was developed and statistically tested to estimate the magnitude of sonicator parameters required to obtain specified MWNT macrodispersions (i.e., aggregates' mean diameter and distribution) in water. The results showed that MWNT aggregates of 2 ± 0.5 μm can be obtained by optimizing sonicator parameters to a sonication time of 89 s, amplitude of 144 μm, and pulse-on/off cycle of 44/30 s. These process settings for 100 mg/L MWNTs in a 30 mL aliquot of deionized water would consume 863 J/mL of sonication energy. Contrary to the popular belief, "sonication time" and/or "sonication energy input" were not found to be proportional to the degree of dispersion of MWNTs in water. This might be the reason for the frequent disparity and nonreproducibility of sonication results reported in scientific literature, especially for dispersing nanomaterials in a number of different systems. The amplitude of vibration was noted to be the most sensitive parameter affecting MWNT aggregates' diameter and distribution in water. The characterization of MWNTs was performed using electron microscopy, surface area analyzer, thermogravimetric analyzer, and zeta potential analyzer. This study can be helpful in evaluating sonication dispersion of particulate matter in other incompressible fluids such as graphene dispersion in organic solvents.

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Modeling of the stability of water-based graphite dispersions using polyvinylpyrrolidone on the basis of the DLVO theory.

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Modeling of the stability of water-based graphite dispersions using polyvinylpyrrolidone on the basis of the DLVO theory.

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