Direct Determination of Peroxide Explosives on Polycarbazole/Gold Nanoparticle-Modified Glassy Carbon Sensor Electrodes Imprinted for Molecular Recognition of TATP and HMTD.

ABSTRACT: Since peroxide-based explosives (PBEs) lack reactive functional groups, they cannot be determined directly by most detection methods and are often detected indirectly by converting them to H₂O₂. However, H₂O₂ may originate from many sources, causing false positives in PBE detection. Here, we developed a novel electrochemical sensor for the direct sensitive and selective determination of PBEs such as triacetone triperoxide (TATP) and hexamethylene triperoxide diamine (HMTD) using electrochemical modification of the glassy carbon (GC) electrode with PBE-memory polycarbazole (PCz) films decorated with gold nanoparticles (AuNPs) by cyclic voltammetry (CV). The prepared electrodes were named TATP-memory-GC/PCz/AuNPs (used for TATP determination) and H

SUBMITTER: Saglam S 

PROVIDER: S-EPMC9773174 | biostudies-literature | 2022 Dec

REPOSITORIES: biostudies-literature