Coordination Polymers Constructed from an Adaptable Pyridine-Dicarboxylic Acid Linker: Assembly, Diversity of Structures, and Catalysis.

ABSTRACT: 4,4'-(Pyridine-3,5-diyl)dibenzoic acid (H₂pdba) was explored as an adaptable linker for assembling a diversity of new manganese(II), cobalt(II/III), nickel(II), and copper(II) coordination polymers (CPs): [Mn(μ₄-pdba)(H₂O)]_n (1), {[M(μ₃-pdba)(phen)]·2H₂O}_n (M = Co (2), Ni (3)), {[Cu₂(μ₃-pdba)₂(bipy)]·2H₂O}_n (4), {[Co(μ₃-pdba)(bipy)]·2H₂O}_n (5), [Co₂(μ₃-pdba)(μ-Hbiim)₂(Hbiim)]_n (6), and [M(μ₄-pdba)(py)]_n (M = Co (7), Ni (8)). The CPs were hydrothermally synthesized us

SUBMITTER: Cheng X 

PROVIDER: S-EPMC9775464 | biostudies-literature | 2022 Nov

REPOSITORIES: biostudies-literature