Mesomorphic, Computational Investigations and Dyeing Applications of Laterally Substituted Dyes.
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ABSTRACT: Two groups of laterally substituted non-mesomorphic and liquid crystalline materials bearing monoazo group were prepared and investigated via experimental and theoretical techniques. The molecular structures of the designed dyes were evaluated by FT-IR and NMR spectroscopic analyses. Mesomorphic examinations for all synthesized dyes were investigated by polarized optical microscopy (POM) and differential scanning calorimetry (DSC). Results revealed that, the thermal and optical properties of investigated compounds are mainly dependent on their molecular geometry. The optimized geometries of the azo derivatives and their electronic absorption of the dyes were carried out using the B3LYP/6-311G level of the DFT method. The azo dyes were measured for their dyeing performance on polyester fabr
SUBMITTER: Ahmed HA
PROVIDER: S-EPMC9785732 | biostudies-literature | 2022 Dec
REPOSITORIES: biostudies-literature
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