Polymeric Nanoparticles with Embedded Eu(III) Complexes as Molecular Probes for Temperature Sensing.

ABSTRACT: Three novel luminescent Eu(III) complexes, Eu1-Eu3, have been synthesized and characterized with CHN analysis, mass-spectrometry and ¹H NMR spectroscopy. The complexes display strong emission in dichloromethane solution upon excitation at 405 and 800 nm with a quantum yield from 18.3 to 31.6%, excited-state lifetimes in the range of 243-1016 ms at 20 °C, and lifetime temperature sensitivity of 0.9%/K (Eu1), 1.9%/K (Eu2), and 1.7%/K (Eu3). The chromophores were embedded into biocompatible latex nanoparticles (NPs_Eu1-NPs_Eu3) that prevented emission quenching and kept the photophysical characteristics of emitters unchanged with the highest temperature sensitivity of 1.3%/K (NPs_Eu2). For this probe cytotoxicity, internalizat

SUBMITTER: Kuznetsov KM 

PROVIDER: S-EPMC9785794 | biostudies-literature | 2022 Dec

REPOSITORIES: biostudies-literature