Unsymmetrical Strategy on α-Diimine Nickel and Palladium Mediated Ethylene (Co)Polymerizations.

ABSTRACT: Among various catalyst design strategies used in the α-diimine nickel(II) and palladium(II) catalyst systems, the unsymmetrical strategy is an effective and widely utilized method. In this contribution, unsymmetrical nickel and palladium α-diimine catalysts (Ipty/ⁱPr-Ni and Ipty/ⁱPr-Pd) derived from the dibenzobarrelene backbone were constructed via the combination of pentiptycenyl and diisopropylphenyl substituents, and investigated toward ethylene (co)polymerization. Both of these catalysts were capable of polymerizing ethylene in a broad temperature range of 0-120 °C, in which Ipty/ⁱPr-Ni could maintain activity in the level of 10⁶ g mol^-1 h^-1 even at 120 °C. The branching densiti

SUBMITTER: Ma X 

PROVIDER: S-EPMC9785926 | biostudies-literature | 2022 Dec

REPOSITORIES: biostudies-literature