The Solution Properties of Polymethacrylate Molecular Brushes with Oligo(ethylene glycol) and Oligo(propylene glycol) Side Chains.

ABSTRACT: The properties of polymer brushes based on three macromonomers were investigated in aqueous and organic solutions. Methacrylic monomers with different compositions of the oligo(oxyalkylene) substituents and arrangements of the oligo(ethylene glycol) and oligo(propylene glycol) blocks were used for the synthesis of polymers. There were methoxy [oligo(ethylene glycol)_10.3-block-oligo(propylene glycol)_4.7] methacrylate, methoxy [oligo(propylene glycol)_8.3-block-oligo(ethylene glycol)_6.6] methacrylate, and methoxy oligo(propylene glycol)_4.2 methacrylate. Molecular brushes were investigated by the methods of molecular hydrodynamics and optics in dilute solutions in acetonitrile, chloroform, and water. The peculiarities of behavior of poly[o

SUBMITTER: Simonova M 

PROVIDER: S-EPMC9786129 | biostudies-literature | 2022 Dec

REPOSITORIES: biostudies-literature