π-Stacks of radical-anionic naphthalenediimides in a metal-organic framework.

ABSTRACT: Radical-ionic metal-organic frameworks (MOFs) have unique optical, magnetic, and electronic properties. These radical ions, forcibly formed by external stimulus-induced redox processes, are structurally unstable and have short radical lifetimes. Here, we report two naphthalenediimide-based (NDI-based) Ca-MOFs: DGIST-6 and DGIST-7. Neutral DGIST-6, which is generated first during solvothermal synthesis, decomposes and is converted into radical-anionic DGIST-7. Cofacial (NDI)₂^•- and (NDI)₂^2- dimers are effectively stabilized in DGIST-7 by electron delocalization and spin-pairing as well as dimethylammonium counter cations in their pores. Single-crystal x-ray diffractometry was used to visualize redox-associated structural transformations, such as c

SUBMITTER: Kim B 

PROVIDER: S-EPMC9788762 | biostudies-literature | 2022 Dec

REPOSITORIES: biostudies-literature