Electroreductive coupling of benzaldehyde by balancing the formation and dimerization of the ketyl intermediate.

ABSTRACT: Electroreductive coupling of biomass-derived benzaldehyde offers a sustainable approach to producing value-added hydrobenzoin. The low efficiency of the reaction mainly ascribes to the mismatch of initial formation and subsequent dimerization of ketyl intermediates (Ph-CH = O → Ph-C·-OH → Ph-C(OH)-C(OH)-Ph). This paper describes a strategy to balance the active sites for the generation and dimerization of ketyl intermediates by constructing bimetallic Pd/Cu electrocatalysts with tunable surface coverage of Pd. A Faradaic efficiency of 63.2% and a hydrobenzoin production rate of up to 1.27 mmol mg^-1 h^-1 (0.43 mmol cm^-2 h^-1) are achieved at -0.40 V vs. reversible hydrogen electrode. Experimental results and theoretical calculations reveal that Pd p

SUBMITTER: Yu J 

PROVIDER: S-EPMC9789095 | biostudies-literature | 2022 Dec

REPOSITORIES: biostudies-literature