Simultaneous Recognition and Separation of Organic Isomers Via Cooperative Control of Pore-Inside and Pore-Outside Interactions.

ABSTRACT: Despite the desirability of organic isomer recognition and separation, current strategies are expensive and complicated. Here, a simple strategy for simultaneously recognizing and separating organic isomers using pillararene-based charge-transfer cocrystals through the cooperative control of pore-inside and pore-outside intermolecular interactions is presented. This strategy is illustrated using 1-bromobutane (1-BBU), which is often produced as an isomeric mixture with 2-bromobutane (2-BBU). According to its structure, perethylated pillar[5]arene (EtP5) and 3,5-dinitrobenzonitrile (DNB) are strategically chosen as a donor and an acceptor. As a result, their cocrystal exhibited stronger pore-inside interactions and much weaker pore-outside interactions with 1-BBU than with 2-BBU. Consequent

SUBMITTER: Xue S 

PROVIDER: S-EPMC9798982 | biostudies-literature | 2022 Dec

REPOSITORIES: biostudies-literature