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Isotopic evidence for pallasite formation by impact mixing of olivine and metal during the first 10 million years of the Solar System.

ABSTRACT: Pallasites are mixtures of core and mantle material that may have originated from the core-mantle boundary of a differentiated body. However, recent studies have introduced the possibility that they record an impact mix, in which case an isotopic difference between metal and silicates in pallasites may be expected. We report a statistically significant oxygen isotope disequilibrium between olivine and chromite in main group pallasites that implies the silicate and metal portions of these meteorites stem from distinct isotopic reservoirs. This indicates that these meteorites were formed by impact mixing, during which a planetary core was injected into the mantle of another body. The impactor likely differentiated within ∼1-2 Myr of the start of the Solar System based on Hf-W chronology of pallasite metal, and we infer the age of the impact based on Mn-Cr systematics and cooling rates at between ∼1.5 and 9.5 Myr after Ca-Al-rich inclusions (CAIs). When combined with published slow subsolidus cooling rates for these meteorites and considering that several pallasite groups exist, our results indicate that such impacts may be an important stage in the evolution of planetary bodies.

SUBMITTER: Windmill RJ

PROVIDER: S-EPMC9802258 | biostudies-literature | 2022 Mar

REPOSITORIES: biostudies-literature

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Isotopic evidence for pallasite formation by impact mixing of olivine and metal during the first 10 million years of the Solar System.

Windmill Richard J RJ Franchi Ian A IA Hellmann Jan L JL Schneider Jonas M JM Spitzer Fridolin F Kleine Thorsten T Greenwood Richard C RC Anand Mahesh M

PNAS nexus 20220309 1

Pallasites are mixtures of core and mantle material that may have originated from the core-mantle boundary of a differentiated body. However, recent studies have introduced the possibility that they record an impact mix, in which case an isotopic difference between metal and silicates in pallasites may be expected. We report a statistically significant oxygen isotope disequilibrium between olivine and chromite in main group pallasites that implies the silicate and metal portions of these meteori ...[more]

PMID: 36712802

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Project description:We examined the mineralogical, chemical and isotopic compositions of secondary fluid inclusions in olivine-rich rocks from two active serpentinization systems: the Von Damm hydrothermal field (Mid-Cayman Rise) and the Zambales ophiolite (Philippines). Peridotite, troctolite and gabbroic rocks in these systems contain abundant CH4-rich secondary inclusions in olivine, with less abundant inclusions in plagioclase and clinopyroxene. Olivine-hosted secondary inclusions are chiefly composed of CH4 and minor H2, in addition to secondary minerals including serpentine, brucite, magnetite and carbonates. Secondary inclusions in plagioclase are dominated by CH4 with variable amounts of H2 and H2O, while those in clinopyroxene contain only CH4. We determined hydrocarbon abundances and stable carbon isotope compositions by crushing whole rocks and analysing the released volatiles using isotope ratio monitoring-gas chromatography mass spectrometry. Bulk rock gas analyses yielded appreciable quantities of CH4 and C2H6 in samples from Cayman (4-313 nmol g-1 CH4 and 0.02-0.99 nmol g-1 C2H6), with lesser amounts in samples from Zambales (2-37 nmol g-1 CH4 and 0.004-0.082 nmol g-1 C2H6). Mafic and ultramafic rocks at Cayman exhibit δ13CCH4 values of -16.7‰ to -4.4‰ and δ13CC2H6 values of -20.3‰ to +0.7‰. Ultramafic rocks from Zambales exhibit δ13CCH4 values of -12.4‰ to -2.8‰ and δ13CC2H6 values of -1.2‰ to -0.9‰. Similarities in the carbon isotopic compositions of CH4 and C2H6 in plutonic rocks, Von Damm hydrothermal fluids, and Zambales gas seeps suggest that leaching of fluid inclusions may provide a significant contribution of abiotic hydrocarbons to deep-sea vent fluids and ophiolite-hosted gas seeps. Isotopic compositions of CH4 and C2H6 from a variety of hydrothermal fields hosted in olivine-rich rocks that are similar to those in Von Damm vent fluids further support the idea that a significant portion of abiotic hydrocarbons in ultramafic-influenced vent fluids is derived from fluid inclusions. This article is part of a discussion meeting issue 'Serpentinite in the Earth system'.

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Isotopic evidence for pallasite formation by impact mixing of olivine and metal during the first 10 million years of the Solar System.

Publications

Isotopic evidence for pallasite formation by impact mixing of olivine and metal during the first 10 million years of the Solar System.

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