Influence of interaction between organic cation and inorganic unit in bi-based hybrid perovskites for photoelectronic properties.

ABSTRACT: With the increase of the passion on lead-free perovskites, more and more endeavor focused on halobismuthates. Here, we have introduced the p-iodoaniline and p-phenylenediamine into Bi-based hybrid materials, and two photoactive iodobismuthate named p-phenylenediamine iodobismuthate (PDABI) and p-iodoaniline iodobismuthate (PIDBI) were prepared. Their single structures, band gaps, thermostability and other properties were explored. The structure results revealed that they all have 1D BiI₄ ^- anion chains with edge-shared BiI₆ octahedron. The DFT result revealed that PIDBI had an inherent interaction between the I substituent in p-iodoaniline cation and the Bi atom in inorganic BiI₄ ^- anion chains. The p

SUBMITTER: Han L 

PROVIDER: S-EPMC9803823 | biostudies-literature | 2022 Dec

REPOSITORIES: biostudies-literature