Heavy Alkali Metal Manganate Complexes: Synthesis, Structures and Solvent-Induced Dissociation Effects.

ABSTRACT: Rare examples of heavier alkali metal manganates [{(AM)Mn(CH₂ SiMe₃ )(N^'Ar )₂ }_∞ ] (AM=K, Rb, or Cs) [N^'Ar =N(SiMe₃ )(Dipp), where Dipp=2,6-iPr₂ -C₆ H₃ ] have been synthesised with the Rb and Cs examples crystallographically characterised. These heaviest manganates crystallise as polymeric zig-zag chains propagated by AM⋅⋅⋅π-arene interactions. Key to their preparation is to avoid Lewis base donor solvents. In contrast, using multidentate nitrogen donors encourages ligand scrambling leading to redistribution of these bimetallic manganate compounds into their corresponding homometallic species as witnessed for the complete Li - Cs series. Adding to the few known crystallographically

SUBMITTER: Ballmann GM 

PROVIDER: S-EPMC9804227 | biostudies-literature | 2022 Oct

REPOSITORIES: biostudies-literature