Molecular Electrochemical Reductive Splitting of Dinitrogen with a Molybdenum Complex.

ABSTRACT: Nitrogen reduction under mild conditions (room T and atmospheric P), using a non-fossil source of hydrogen remains a challenge. Molecular metal complexes, notably Mo based, have recently been shown to be active for such nitrogen fixation. We report electrochemical N₂ splitting with a Mo^III triphosphino complex [(PPP)MoI₃ ], at room temperature and a moderately negative potential. A Mo^IV nitride species was generated, which is confirmed by electrochemistry and NMR studies. The reaction goes through two successive one electron reductions of the starting Mo species, coordination of a N₂ molecule, and further splitting to a Mo^IV nitride complex. Preliminary DFT studies support the formation of a bridging Mo^I N_2</

SUBMITTER: Merakeb L 

PROVIDER: S-EPMC9804441 | biostudies-literature | 2022 Oct

REPOSITORIES: biostudies-literature