C-H and Si-H Activation Reactions at Ru/Ga Complexes: A Combined Experimental and Theoretical Case Study on the Ru-Ga Bond.

ABSTRACT: Treatment of [Ru(COD)(MeAllyl)₂ ] and [Ru(COD)(COT)] with GaCp* under hydrogenolytic conditions leads to reactive intermediates which activate Si-H or C-H bonds, respectively. The product complexes [Ru(GaCp*)₃ (SiEt₃ )H₃ ] (1) and [Ru(GaCp*)₃ (C₇ H₇ )H₃ ] (2) are formed with HSiEt₃ or with toluene as the solvent, respectively. While 1 was isolated and fully characterized by NMR, MS, IR and SC-XRD, 2 was too labile to be isolated and was observed and characterized in situ by using mass spectrometry, including labelling experiments for the unambiguous assignment of the elemental composition. The structural assignment was confirmed by DFT calculations. The relative energies of the four isomers p

SUBMITTER: Muhr M 

PROVIDER: S-EPMC9804459 | biostudies-literature | 2022 Sep

REPOSITORIES: biostudies-literature