Observation and Modeling of a Sharp Oxygen Threshold in Aqueous Free Radical and RAFT Polymerization.

ABSTRACT: It is known that oxygen (O₂) stops radical polymerization (RP). Here, it was found that the reaction turn-off occurs abruptly at a threshold concentration of O₂, [O₂]_t, for both free RP and reversible addition-fragmentation chain-transfer polymerization (RAFT). In some reactions, there was a spontaneous re-start of conversion. Three cases were investigated: RP of (i) acrylamide (Am) and (ii) sodium styrene sulfonate (SS) and (iii) Am RAFT polymerization. A controlled flow of O₂ into the reactor was employed. An abrupt turn-off was observed in all cases, where polymerization stops sharply at [O₂]_t and remains stopped when [O₂] > [O₂]_t. In (i), Am acts as a catalytic radical-transfer

SUBMITTER: Siqueira JS 

PROVIDER: S-EPMC9806832 | biostudies-literature | 2022 Dec

REPOSITORIES: biostudies-literature