Insights into the thermodynamic-kinetic synergistic separation of propyne/propylene in anion pillared cage MOFs with entropy-enthalpy balanced adsorption sites.

ABSTRACT: Propyne/propylene (C₃H₄/C₃H₆) separation is an important industrial process yet challenged by the trade-off of selectivity and capacity due to the molecular similarity. Herein, record C₃H₄/C₃H₆ separation performance is achieved by fine tuning the pore structure in anion pillared MOFs. SIFSIX-Cu-TPA (ZNU-2-Si) displays a benchmark C₃H₄ capacity (106/188 cm³ g^-1 at 0.01/1 bar and 298 K), excellent C₃H₄/C₃H₆ IAST selectivity (14.6-19.3) and kinetic selectivity, and record high C₃H₄/C₃H₆ (10/90) separation potential (36.2 mol kg^-1). The practical C₃H

SUBMITTER: Jiang Y 

PROVIDER: S-EPMC9811657 | biostudies-literature | 2023 Jan

REPOSITORIES: biostudies-literature