Dynamic semiconductor-electrolyte interface for sustainable solar water splitting over 600 hours under neutral conditions.

ABSTRACT: Photoelectrochemical (PEC) water splitting that functions in pH-neutral electrolyte attracts increasing attention to energy demand sustainability. Here, we propose a strategy to in situ form a NiB layer by tuning the composition of the neutral electrolyte with the additions of nickel and borate species, which improves the PEC performance of the BiVO₄ photoanode. The NiB/BiVO₄ exhibits a photocurrent density of 6.0 mA cm^-2 at 1.23 V_RHE with an onset potential of 0.2 V_RHE under 1 sun illumination. The photoanode displays a photostability of over 600 hours in a neutral electrolyte. The additive of Ni²⁺ in the electrolyte, which efficiently inhibits the dissolution of NiB, can accelerate the photogenerated charge transfer and en

SUBMITTER: Gao RT 

PROVIDER: S-EPMC9812387 | biostudies-literature | 2023 Jan

REPOSITORIES: biostudies-literature