Fe^III in the high-spin state in dimethylammonium bis[3-ethoxysalicylaldehyde thiosemicarbazonato(2-)-κ³O²,N¹,S]ferrate(III).

ABSTRACT: The synthesis and crystal structure (100 K) of the title compound, [(CH₃)₂NH₂][Fe(C₁₀H₁₁O₂N₃S)₂], are reported. The asymmetric unit consists of an octahedral [Fe^III(L)₂]^- fragment, where L^2- is 3-ethoxysalicylaldehyde thiosemicarbazonate(2-), and a dimethylammonium cation. Each L^2- ligand binds with the thiolate S, the imine N and the phenolate O atoms as donors, resulting in an Fe^IIIS₂N₂O₂ chromophore. The ligands are orientated in two perpendicular planes, with the O and S atoms in cis positions, and mutually trans N atoms. The Fe^III ion is in the high-spin state at 100 K. The variable-tempera

SUBMITTER: Powell RE 

PROVIDER: S-EPMC9813924 | biostudies-literature | 2023 Jan

REPOSITORIES: biostudies-literature