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Understanding the interactions between the bis(trifluoromethylsulfonyl)imide anion and absorbed CO₂ using X-ray diffraction analysis of a soft crystal surrogate.

ABSTRACT: The selective carbon dioxide (CO₂) absorption properties of ionic liquids (ILs) are highly pertinent to the development of methods to capture CO₂. Although it has been reported that fluorinated components give ILs enhanced CO₂ solubilities, it has been challenging to gain a deep understanding of the interactions occurring between ILs and CO₂. In this investigation, we have utilized the soft crystalline material [Cu(NTf₂)₂(bpp)₂] (NTf₂^‒ = bis(trifluoromethylsulfonyl)imide, bpp = 1,3-bis-(4-pyridyl)propane) as a surrogate for single-crystal X-ray diffraction analysis to visualize interactions occurring between CO₂ and NTf₂^‒, the fluorinated IL component that is

SUBMITTER: Zheng X

PROVIDER: S-EPMC9814135 | biostudies-literature | 2020 Oct

REPOSITORIES: biostudies-literature

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Dataset Information

Understanding the interactions between the bis(trifluoromethylsulfonyl)imide anion and absorbed CO₂ using X-ray diffraction analysis of a soft crystal surrogate.

OmicsDI is part of the ELIXIR infrastructure

Tweets

Dataset Information

Understanding the interactions between the bis(trifluoromethylsulfonyl)imide anion and absorbed CO2 using X-ray diffraction analysis of a soft crystal surrogate.

OmicsDI is part of the ELIXIR infrastructure

Tweets

Understanding the interactions between the bis(trifluoromethylsulfonyl)imide anion and absorbed CO₂ using X-ray diffraction analysis of a soft crystal surrogate.