Formation of H₃⁺ from ethane dication induced by electron impact.

ABSTRACT: Hydrogen migration plays an important role in the chemistry of hydrocarbons which considerably influences their chemical functions. The migration of one or more hydrogen atoms occurring in hydrocarbon cations has an opportunity to produce the simplest polyatomic molecule, i.e. H₃⁺. Here we present a combined experimental and theoretical study of H₃⁺ formation dynamics from ethane dication. The experiment is performed by 300 eV electron impact ionization of ethane and a pronounced yield of H₃⁺ + C₂H₃⁺ coincidence channel is observed. The quantum chemistry calculations show that the H₃⁺ formation channel can be opened on the ground-state potential energy surface of ethane

SUBMITTER: Zhang Y 

PROVIDER: S-EPMC9814254 | biostudies-literature | 2020 Nov

REPOSITORIES: biostudies-literature