CO₂ conversion to formamide using a fluoride catalyst and metallic silicon as a reducing agent.

ABSTRACT: Metallic silicon could be an inexpensive, alternative reducing agent for CO₂ functionalization compared to conventionally used hydrogen or hydrosilanes. Here, metallic silicon recovered from solar panel production is used as a reducing agent for formamide synthesis. Various amines are converted to their corresponding amides with CO₂ and H₂O via an Si-H intermediate species in the presence of a catalytic amount of tetrabutylammonium fluoride. The reaction system exhibits a wide substrate scope for formamide synthesis. Spectroscopic analysis, including in situ Fourier transform infrared (FTIR), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), N₂ adsorption/desorption analyses, and isotopic experiments reveal that the fluoride cataly

SUBMITTER: Wang R 

PROVIDER: S-EPMC9814565 | biostudies-literature | 2022 Nov

REPOSITORIES: biostudies-literature