Dataset Information

Efficient alkane oxidation under combustion engine and atmospheric conditions.

ABSTRACT: Oxidation chemistry controls both combustion processes and the atmospheric transformation of volatile emissions. In combustion engines, radical species undergo isomerization reactions that allow fast addition of O₂. This chain reaction, termed autoxidation, is enabled by high engine temperatures, but has recently been also identified as an important source for highly oxygenated species in the atmosphere, forming organic aerosol. Conventional knowledge suggests that atmospheric autoxidation requires suitable structural features, like double bonds or oxygen-containing moieties, in the precursors. With neither of these functionalities, alkanes, the primary fuel type in combustion engines and an important class of urban trace gases, are thought to have minor susceptibility to extensive autoxidation. Here, utilizing state-of-the-art mass spectrometry, measuring both radicals and oxidation products, we show that alkanes undergo autoxidation much more efficiently than previously thought, both under atmospheric and combustion conditions. Even at high concentrations of NO_X, which typically rapidly terminates autoxidation in urban areas, the studied C₆-C₁₀ alkanes produce considerable amounts of highly oxygenated products that can contribute to urban organic aerosol. The results of this inter-disciplinary effort provide crucial information on oxidation processes in both combustion engines and the atmosphere, with direct implications for engine efficiency and urban air quality.

SUBMITTER: Wang Z

PROVIDER: S-EPMC9814728 | biostudies-literature | 2021 Feb

REPOSITORIES: biostudies-literature

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Efficient alkane oxidation under combustion engine and atmospheric conditions.

Wang Zhandong Z Ehn Mikael M Rissanen Matti P MP Garmash Olga O Quéléver Lauriane L Xing Lili L Monge-Palacios Manuel M Rantala Pekka P Donahue Neil M NM Berndt Torsten T Sarathy S Mani SM

Communications chemistry 20210218 1

Oxidation chemistry controls both combustion processes and the atmospheric transformation of volatile emissions. In combustion engines, radical species undergo isomerization reactions that allow fast addition of O<sub>2</sub>. This chain reaction, termed autoxidation, is enabled by high engine temperatures, but has recently been also identified as an important source for highly oxygenated species in the atmosphere, forming organic aerosol. Conventional knowledge suggests that atmospheric autoxid ...[more]

PMID: 36697513

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Project description:A micro-reciprocating piston internal combustion engine with liquid hydrocarbon fuel has the potential to supply ultrahigh density energy to micro electro mechanical system because of its high-density energy, simple structure, and mature energy conversion principle. However, the diagnostic test of the combustion characteristics of the micro reciprocating piston internal combustion engine shows that its combustion characteristics are poor, and the combustion rate was lower with the combustion duration of more than 50 °CA. The mean indicated pressure (Pmi) value was only 0.137 MPa, the combustion stability was very poor, and the cycle variation rate of the Pmi was up to 60%. To improve its combustion performance, the method to enhance combustion in micro-space is explored then. Mechanism studies have shown that the pyrolysis reaction of nitromethane and hydrogen peroxide can produce amounts of free radicals OH, with the possibility of improving the combustion of methanol. Therefore, a method for adjusting the composition of methanol fuel to enhance combustion is proposed, and the method is theoretically confirmed. Finally, based on this method, the test was carried out. The results showed that the combustion rate increased and the combustion duration decreased by 6% after adding nitromethane. The power performance was enhanced, and the Pmi value was increased by 30%. The combustion stability was enhanced, and the cycle variation rate of the Pmi was reduced to 16.9%. Nitromethane has a significant effect on improving the combustion characteristics of methanol, and the enhancement of the latter was mainly reflected in the ignition phase of the combustion process. This study indicates that exploring the fuel additive that can increase the concentration of OH radical in the reaction is an effective method to improve the micro-space combustion, which will facilitate the development of micro-piston internal combustion engine to supply energy to a micro electro mechanical system.

Dataset Information

Efficient alkane oxidation under combustion engine and atmospheric conditions.

Publications

Efficient alkane oxidation under combustion engine and atmospheric conditions.

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