Towards deeper understanding of multifaceted chemistry of magnesium alkylperoxides.

ABSTRACT: Despite considerable progress in the multifaceted chemistry of non-redox-metal alkylperoxides, the knowledge about magnesium alkylperoxides is in its infancy and only started to gain momentum. Harnessing the well-defined dimeric magnesium tert-butylperoxide [(^f5BDI)Mg(μ-η²:η¹-OOtBu)]₂ incorporating a fluorinated β-diketiminate ligand, herein, we demonstrate its transformation at ambient temperature to a spiro-type, tetranuclear magnesium alkylperoxide [(^f5BDI)₂Mg₄(μ-OOtBu)₆]. The latter compound was characterized by single-crystal X-ray diffraction and its molecular structure can formally be considered as a homoleptic magnesium tert-butylperoxide [Mg(µ-OOtBu)₂]₂ terminated by two m

SUBMITTER: Pietrzak T 

PROVIDER: S-EPMC9814855 | biostudies-literature | 2021 Aug

REPOSITORIES: biostudies-literature