Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Di-chlorido-(4,4'-dimethyl-2,2'-bi-pyridine-κ² N,N')zinc(II) aceto-nitrile monosolvate.

ABSTRACT: In the title complex, [ZnCl₂(C₁₂H₁₂N₂)]·CH₃CN, the zinc(II) atom is fourfold coordinated by two chloride ligands and a bidentate 4,4'-dimethyl-2,2'-bi-pyridine ligand in a distorted tetra-hedral shape with a mol-ecule of aceto-nitrile sitting in the outer coordination sphere of the complex. π-π stacking inter-actions between the pyridyl rings in adjacent mol-ecules contribute to the alignment of the complexes in columns parallel to the a axis.

SUBMITTER: Adrian RA

PROVIDER: S-EPMC9815126 | biostudies-literature | 2022 Dec

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Di-chlorido-(4,4'-dimethyl-2,2'-bi-pyridine-κ2 N,N')zinc(II) aceto-nitrile monosolvate.

Adrian Rafael A RA Rios Jadan J JJ Arman Hadi D HD

IUCrData 20221206 Pt 12

In the title complex, [ZnCl2(C12H12N2)]·CH3CN, the zinc(II) atom is fourfold coordinated by two chloride ligands and a bidentate 4,4'-dimethyl-2,2'-bi-pyridine ligand in a distorted tetra-hedral shape with a mol-ecule of aceto-nitrile sitting in the outer coordination sphere of the complex. π-π stacking inter-actions between the pyridyl rings in adjacent mol-ecules contribute to the alignment of the complexes in columns parallel to the a< ...[more]

PMID: 36628194

Similar Datasets

(2,2′-Bipyridine-κ2N,N′)(4,4′-dimethoxy-2,2′-bipyridine-κ2N,N′)palladium(II) bis(trifluoromethanesulfonate)

Project description: Not available

| S-EPMC10915546 | biostudies-literature

Diacetonitrile(2,2′-bipyridine-κ2N,N′)palladium(II) bis(trifluoromethanesulfonate)

Project description:In the crystal structure of the title compound, the palladium(II) metal center is surrounded by a bidentate 2,2′-bipyridine ligand and two acetonitrile molecules in a distorted square-planar geometry. In the title complex, [Pd(C10H8N2)(CH3CN)2](CF3SO3)2 or [Pd(bipy)(CH3CN)2](CF3SO3)2, the palladium(II) ion is fourfold coordinated by two acetonitrile molecules and a bidentate 2,2′-bipyridine ligand in a distorted square-planar geometry.

| S-EPMC9815130 | biostudies-literature

catena-Poly[[(2,2′-bipyridine-κ2N,N′)manganese(II)]-di-μ-bromido]

Project description:The central MnII ion has a cis-N2Br4 octahedral coordination sphere defined by two N atoms of the bidentate 2,2′-bipyridine ligand and four bridging Br− anions. In the polymeric title complex, [MnBr2(C10H8N2)]n, the MnII ion, situated on a twofold axis of symmetry, is six-coordinated in a distorted octahedral coordination geometry defined by two N atoms from the chelating 2,2′-bipyridine ligand and four bridging Br− anions. The crystal reveals a one-dimensional Br-bridged chain along the c-axis direction with a zigzag topology. In the crystals, contacts between chains include π–π interactions between pyridyl rings [inter-centroid separation = 4.082 (1) Å]

| S-EPMC9462262 | biostudies-literature

Aquabis(2,2′-bipyridine-κ2N,N′)(isonicotinamide-κN)ruthenium(II) bis(trifluoromethanesulfonate)

Project description: Not available

| S-EPMC10915547 | biostudies-literature

Dibromido(4,4'-dimethyl-2,2'-bipyridine-κN,N')zinc(II).

Project description:The asymmetric unit of the title compound, [ZnBr(2)(C(12)H(12)N(2))], contains two half-mol-ecules; both are completed by crystallographic twofold axes running through the Zn(II) atoms which are coordinated by an N,N'-bidentate 4,4'-dimethyl-2,2'-bipyridine ligand and two Br(-) ions, resulting in distorted ZnN(2)Br(2) tetra-hedral coordination geometries. In the crystal, C-H⋯Br inter-actions link the mol-ecules.

| S-EPMC3007259 | biostudies-literature

Chlorido(4′-chloro-2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)(trifluoromethanesulfonato-κO)zinc(II) acetonitrile monosolvate

Project description:The title compound structure is a unique example of a zinc(II) metal center surrounded by a tridentate chloroterpyridine ligand, a chloride and a coordinated trifluoromethanesulfonate in a distorted square-pyramidal geometry. In the title complex, [Zn(CF3O3S)Cl(C15H10ClN3)]·CH3CN, the zinc(II) core is fivefold coordinated by one chloride, one trifluoromethanesulfonate O atom and three terpyridine N atoms in a slightly distorted square-pyramidal geometry. The structure provides a distinct example amongst other zinc(II) 4-chloroterpyridine complexes because of the unusual planarity of the coordinated chloride, the short length of the Zn—N bond opposite to the chloride ligand [1.9572 (15) Å], and the presence of an elongated Zn—O bond [2.3911 (14) Å] in the coordinated trifluoromethanesulfonate ion. A molecule of acetonitrile is also found in the asymmetric unit of the title complex.

| S-EPMC9462286 | biostudies-literature

(4-Aminopyridine-κN1)(2,2′-bipyridine-κ2N,N′)(2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)ruthenium(II) bis(hexafluoridophosphate) unknown solvate

Project description:The ruthenium dication and hexafluoridophosphate anions of the title salt are linked by N—H⋯F hydrogen bonds at the amino group of the substituted pyridine ring. The Ru—N bond lengths show the expected range. The title compound, [Ru(C5H6N2)(C10H8N2)(C15H11N3)](PF6)2 solvent, crystallizes in the triclinic space group P

| S-EPMC9462321 | biostudies-literature

Bis(μ-2,2'-oxydibenzoato-κO,O':O'',O''')bis-[(4,4'-dimethyl-2,2'-bipyridine-κN,N')zinc(II)] dihydrate.

Project description:In the title compound, [Zn(2)(C(14)H(8)O(5))(2)(C(12)H(12)N(2))(2)]·2H(2)O, the Zn(II) atom exhibits a distorted octa-hedral coordination geometry, defined by two N atoms from one 4,4'-dimethyl-2,2'-bipyridine ligand and four O atoms from two bridging 2,2'-oxydibenzoate ligands. The mol-ecule is a centrosymmetric dimer. π-π Stacking inter-actions are observed between the 4,4'-dimethyl-2,2'-bipyridine ligands, with a centroid-centroid distance of 3.649 (2) Å.

| S-EPMC2961073 | biostudies-literature

(4,4'-Dimethyl-2,2'-bipyridine-κN,N')diiodidomercury(II).

Project description:In the mol-ecule of the title compound, [HgI(2)(C(12)H(12)N(2))], the Hg(II) atom is four-coordinated in a distorted tetra-hedral configuration by two N atoms from the 4,4'-dimethyl-2,2'-bipyridine ligand and by two I atoms. There is a π-π contact between the pyridine rings [centroid-centroid distance = 3.775 (6) Å].

| S-EPMC2959485 | biostudies-literature

(4,4'-Dimethyl-2,2'-bipyridine-κN,N')(dimethyl sulfoxide-κO)diiodidozinc(II).

Project description:In the title compound, [ZnI(2)(C(12)H(12)N(2))(C(2)H(6)OS)], the Zn(II) ion is coordinated by two N atoms from a 4,4'-dimethyl-2,2'-bipyridine ligand, one O atom from a dimethyl sulfoxide mol-ecule and two I atoms in a distorted trigonal-bipyramidal geometry. Intra-molecular C-H⋯O hydrogen bonds and inter-molecular π-π stacking inter-actions between the pyridine rings [centroid-centroid distances = 3.637 (4) and 3.818 (4) Å] are present in the crystal structure.

| S-EPMC3011543 | biostudies-literature