Dataset Information

Fabrication of r-GO/GO/α-Fe₂O₃/Fe₂TiO₅ Nanocomposite Using Natural Ilmenite and Graphite for Efficient Photocatalysis in Visible Light.

ABSTRACT: Hematite (α-Fe₂O₃) and pseudobrookite (Fe₂TiO₅) suffer from poor charge transport and a high recombination effect under visible light irradiation. This study investigates the design and production of a 2D graphene-like r-GO/GO coupled α-Fe₂O₃/Fe₂TiO₅ heterojunction composite with better charge separation. It uses a simple sonochemical and hydrothermal approach followed by L-ascorbic acid chemical reduction pathway. The advantageous band offset of the α-Fe₂O₃/Fe₂TiO₅ (TF) nanocomposite between α-Fe₂O₃ and Fe₂TiO₅ forms a Type-II heterojunction at the Fe₂O₃/Fe₂TiO₅ interface, which efficiently promotes electron-hole separation. Importantly, very corrosive acid leachate resulting from the hydrochloric acid leaching of ilmenite sand, was successfully exploited to fabricate α-Fe₂O₃/Fe₂TiO₅ heterojunction. In this paper, a straightforward synthesis strategy was employed to create 2D graphene-like reduced graphene oxide (r-GO) from Ceylon graphite. The two-step process comprises oxidation of graphite to graphene oxide (GO) using the improved Hummer's method, followed by controlled reduction of GO to r-GO using L-ascorbic acid. Before the reduction of GO to the r-GO, the surface of TF heterojunction was coupled with GO and was allowed for the controlled L-ascorbic acid reduction to yield r-GO/GO/α-Fe₂O₃/Fe₂TiO₅ nanocomposite. Under visible light illumination, the photocatalytic performance of the 30% GO/TF loaded composite material greatly improved (1240 Wcm^-2). Field emission scanning electron microscopy (FE-SEM) and high-resolution transmission electron microscopy (HR-TEM) examined the morphological characteristics of fabricated composites. X-ray photoelectron spectroscopy (XPS), Raman, X-ray diffraction (XRD), X-ray fluorescence (XRF), and diffuse reflectance spectroscopy (DRS) served to analyze the structural features of the produced composites.

SUBMITTER: Usgodaarachchi L

PROVIDER: S-EPMC9821193 | biostudies-literature | 2022 Dec

REPOSITORIES: biostudies-literature

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Fabrication of r-GO/GO/α-Fe2O3/Fe2TiO5 Nanocomposite Using Natural Ilmenite and Graphite for Efficient Photocatalysis in Visible Light.

Usgodaarachchi Leshan L Jayanetti Madara M Thambiliyagodage Charitha C Liyanaarachchi Heshan H Vigneswaran Saravanamuthu S

Materials (Basel, Switzerland) 20221223 1

Hematite (α-Fe2O3) and pseudobrookite (Fe2TiO5) suffer from poor charge transport and a high recombination effect under visible light irradiation. This study investigates the design and production of a 2D graphene-like r-GO/GO coupled α-Fe2O3/Fe2TiO5 heterojunction composite with better charge separation. It uses a simple sonochemical and hydrothermal approach followed by L-ascorbic acid chemical reduction pa ...[more]

PMID: 36614479

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Project description:Dyes in wastewater are a serious problem that needs to be resolved. Adsorption coupled photocatalysis is an innovative technique used to remove dyes from contaminated water. Novel composites of TiO2-Fe3C-Fe-Fe3O4 dispersed on graphitic carbon were fabricated using natural ilmenite sand as the source of iron and titanium, and sucrose as the carbon source, which were available at no cost. Synthesized composites were characterized by X-ray diffractometry (XRD), Raman spectroscopy, transmission electron microscopy (TEM), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), X-ray fluorescence spectroscopy (XRF), and diffuse reflectance UV-visible spectroscopy (DRS). Arrangement of nanoribbons of graphitic carbon with respect to the nanomaterials was observed in TEM images, revealing the occurrence of catalytic graphitization. Variations in the intensity ratio (I D/I G), L a and L D, calculated from data obtained from Raman spectroscopy suggested that the level of graphitization increased with an increased loading of the catalysts. SEM images show the immobilization of nanoplate microballs and nanoparticles on the graphitic carbon matrix. The catalyst surface consists of Fe3+ and Ti4+ as the metal species, with V, Mn, and Zr being the main impurities. According to DRS spectra, the synthesized composites absorb light in the visible region efficiently. Fabricated composites effectively adsorb methylene blue via π-π interactions, with the absorption capacities ranging from 21.18 to 45.87 mg/g. They were effective in photodegrading methylene blue under sunlight, where the rate constants varied in the 0.003-0.007 min-1 range. Photogenerated electrons produced by photocatalysts captured by graphitic carbon produce O2 •- radicals, while holes generate OH• radicals, which effectively degrade methylene blue molecules. TiO2-Fe3C-Fe-Fe3O4/graphitic carbon composites inhibited the growth of Escherichia coli (69%) and Staphylococcus aureus (92%) under visible light. Synthesized novel composites using natural materials comprise an ecofriendly, cost-effective solution to remove dyes, and they were effective in inhibiting the growth of Gram-negative and Gram-positive bacteria.

Dataset Information

Fabrication of r-GO/GO/α-Fe₂O₃/Fe₂TiO₅ Nanocomposite Using Natural Ilmenite and Graphite for Efficient Photocatalysis in Visible Light.

Publications

Fabrication of r-GO/GO/α-Fe<sub>2</sub>O<sub>3</sub>/Fe<sub>2</sub>TiO<sub>5</sub> Nanocomposite Using Natural Ilmenite and Graphite for Efficient Photocatalysis in Visible Light.

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