Effect of Water Vapor on Oxidation Processes of the Cu(111) Surface and Sublayer.

ABSTRACT: Copper-based catalysts have different catalytic properties depending on the oxidation states of Cu. We report operando observations of the Cu(111) oxidation processes using near-ambient pressure scanning tunneling microscopy (NAP-STM) and near-ambient pressure X-ray photoelectron spectroscopy (NAP-XPS). The Cu(111) surface was chemically inactive to water vapor, but only physisorption of water molecules was observed by NAP-STM. Under O₂ environments, dry oxidation started at the step edges and proceeded to the terraces as a Cu₂O phase. Humid oxidation of the H₂O/O₂ gas mixture was also promoted at the step edges to the terraces. After the Cu₂O covered the surface under humid conditions, hydroxides and adsorbed water layers formed. NAP-

SUBMITTER: Kim YJ 

PROVIDER: S-EPMC9821670 | biostudies-literature | 2023 Jan

REPOSITORIES: biostudies-literature