Synthesis and Structural Characterization of Phosphanide Gold(III)/Gold(I) Complexes and Their Thallium(III) and Gold(III) Precursors.

ABSTRACT: In this paper, we describe a series of diphenylphosphane and diphenylphosphanide gold(III) and gold(III)/gold(I) complexes containing 3,5-C₆Cl₂F₃ as aryl ligands at gold that have been synthesized due to the arylating and oxidant properties of the new polymeric thallium(III) complex [TlCl(3,5-C₆Cl₂F₃)₂]_n (1). Its reaction with [Au(3,5-C₆Cl₂F₃)(tht)] (tht = tetrahydrothiophene) produces the gold(III) complex [Au(3,5-C₆Cl₂F₃)₃(tht)] (2), which allows the synthesis of the diphenylohosphane derivative [Au(3,5-C₆Cl₂F₃)₃(PPh₂H)] (3). Its treatment with acetyl

SUBMITTER: Coconubo-Guio L 

PROVIDER: S-EPMC9824866 | biostudies-literature | 2023 Jan

REPOSITORIES: biostudies-literature