Oxidative Fluorination of Selenium and Tellurium Compounds using a Thermally Stable Phosphonium SF₅ ^- Salt Accessible from SF₆.

ABSTRACT: Fluorinated group 16 moieties are attractive building blocks in synthetic chemistry but only few synthetic methods are available to prepare them. Herein, we report a new oxidative fluorination reagent capable of stabilizing reactive fluorinated anions. It consists of an SF₅ ^- anion and a chemically inert phosphonium cation and is exceptionally thermally stable. Accordingly, it was used to generate the SeF₅ ^- and TeF₅ ^- anions from the elemental chalcogens and to prepare the unknown tetrafluoro(phenyl)-λ⁵ -selenate PhSeF₄ ^- and -tellurate PhTeF₄ ^- from the corresponding diphenyl dichalcogenides. In addition, we show that further derivatization of [PhTeF₄ ]

SUBMITTER: Eder T 

PROVIDER: S-EPMC9826459 | biostudies-literature | 2022 Oct

REPOSITORIES: biostudies-literature