Photophysical and anion sensing properties of a triphenylamine-dioxaborinine trimeric compound.

ABSTRACT: Herein, we report the synthesis and photophysical characterization of the novel tris(4-(2,2-difluoro-6-methyl-2H-1λ³,3,2λ⁴-dioxaborinin-4-yl)phenyl)amine trimeric probe (A2) via the reaction between triphenylamine (1), acetic anhydride, and BF₃·OEt₂ implying the twelve new bond formation in a one-pot manner. This highly fluorescent compound in solution (φ up to 0.91 at 572 nm) and solid state (φ = 0.24 at 571 nm) showed a better solvatofluorochromism than its analog monomeric A1 due to symmetry-broken charge transfer, which is consistent with high solvent dipolarity (SdP) response in Catalán's multiparametric regression. Notably, A2 had a high sensibility and selectivity for CN^- or F^- in solution

SUBMITTER: Tigreros A 

PROVIDER: S-EPMC9828043 | biostudies-literature | 2023 Jan

REPOSITORIES: biostudies-literature