A gradient oxy-thiophosphate-coated Ni-rich layered oxide cathode for stable all-solid-state Li-ion batteries.

ABSTRACT: High-energy Ni-rich layered oxide cathode materials such as LiNi_0.8Mn_0.1Co_0.1O₂ (NMC811) suffer from detrimental side reactions and interfacial structural instability when coupled with sulfide solid-state electrolytes in all-solid-state lithium-based batteries. To circumvent this issue, here we propose a gradient coating of the NMC811 particles with lithium oxy-thiophosphate (Li₃P_1+xO₄S_4x). Via atomic layer deposition of Li₃PO₄ and subsequent in situ formation of a gradient Li₃P_1+xO₄S_4x coating, a precise and conformal covering for NMC811 particles is obtained. The tailored surface structure and chemistry of NMC811 hinder the structural d

SUBMITTER: Liang J 

PROVIDER: S-EPMC9832028 | biostudies-literature | 2023 Jan

REPOSITORIES: biostudies-literature