An electric molecular motor.

ABSTRACT: Macroscopic electric motors continue to have a large impact on almost every aspect of modern society. Consequently, the effort towards developing molecular motors^1-3 that can be driven by electricity could not be more timely. Here we describe an electric molecular motor based on a [3]catenane^4,5, in which two cyclobis(paraquat-p-phenylene)⁶ (CBPQT⁴⁺) rings are powered by electricity in solution to circumrotate unidirectionally around a 50-membered loop. The constitution of the loop ensures that both rings undergo highly (85%) unidirectional movement under the guidance of a flashing energy ratchet^7,8, whereas the interactions between the two rings give rise to a two-dimensional potential energy surface (PES) similar to that shown by F

SUBMITTER: Zhang L 

PROVIDER: S-EPMC9834048 | biostudies-literature | 2023 Jan

REPOSITORIES: biostudies-literature