Ni-Catalyzed Regioselective Reductive 1,3-Dialkenylation of Alkenes.

ABSTRACT: Dicarbofunctionalization is an important efficient synthetic technique for adding two chemical moieties across an alkene. Here, a novel method of reductive dicarbofunctionalization has been developed using a single alkenyl triflate as the electrophile, combined with an unactivated alkene. The reaction does not require an external auxiliary and proceeds with complete regioselectivity.

SUBMITTER: Wickham LM 

PROVIDER: S-EPMC9835523 | biostudies-literature | 2023 Jan

REPOSITORIES: biostudies-literature