Programming Thermochromic Liquid Crystal Hetero-Oligomers for Near-Infrared Reflectors: Unequal Incorporation of Similar Reactive Mesogens in Thiol-ene Oligomers.

ABSTRACT: Cholesteric liquid crystal oligomers are widely researched for their interesting thermochromic properties. However, structure-property relationships to program the thermochromic properties of these oligomers have been rarely reported. In this work, we use the versatile thiol-ene click reaction to synthesize a series of hetero-oligomers and study the impact of different compositions on the thermochromic behavior of the resulting material. Characterization of the oligomers shows significantly different rates of reaction for the monomers despite their very similar structures, which leads to oligomer compositions that do not match the original reaction feed. The oligomers are then used to produce thin near-infrared reflecting coatings. The best-performing thermochromic reflector has a room-tem

SUBMITTER: Sentjens H 

PROVIDER: S-EPMC9835980 | biostudies-literature | 2023 Jan

REPOSITORIES: biostudies-literature