Reversible trans-to-cis photoisomerization and irreversible photocyclization reactions of a Co-coordinated stilbene derivative on chiral di-β-diketonate lanthanide complexes.

ABSTRACT: Six lanthanide complexes constructed from two chiral β-diketonates (d/l-fbc = 3-heptafluorobutyryl-(+)/(-)-camphorate), the stilbene derivative (E)-N',N'-bis(pyridin-2-ylmethyl)-4-styrylbenzoyl hydrazide (L), a trifluoroacetate anion (CF₃CO₂ ^-), and one water molecule, namely [Ln(d/l-fbc)₂(L)(CF₃CO₂)]·H₂O (LnC₅₇H₅₄F₁₇N₄O₈, Ln = La (1, d-fbc), La (2, l-fbc), Sm (3, d-fbc), Eu (4, d-fbc), Eu (5, l-fbc), and Tb (6, d-fbc), were synthesized and characterized by single-crystal X-ray diffraction, ¹H-NMR, elemental analysis, IR and UV-vis spectroscopy, and thermal gravimetric analysis. The photoisomerization reacti

SUBMITTER: Hou Z 

PROVIDER: S-EPMC9837704 | biostudies-literature | 2023 Jan

REPOSITORIES: biostudies-literature