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Massive abiotic methane production in eclogite during cold subduction.

ABSTRACT: Methane (CH₄) is a critical but overlooked component in the study of the deep carbon cycle. Abiotic CH₄ produced by serpentinization of ultramafic rocks has received extensive attention, but its formation and flux in mafic rocks during subduction remain poorly understood. Here, we report massive CH₄-rich fluid inclusions in well-zoned garnet from eclogites in Western Tianshan, China. Petrological characteristics and carbon-hydrogen isotopic compositions confirm the abiotic origin of this CH₄. Reconstructed P-T-fO₂-fluid trajectories and Deep Earth Water modeling imply that massive abiotic CH₄ was generated during cold subduction at depths of 50-120 km, whereas CO₂ was produced during exhumation. The massive production of abiotic CH₄ in eclogites may result from multiple mechanisms during prograde high pressure-ultrahigh pressure metamorphism. Our flux calculation proposes that abiotic CH₄ that has been formed in HP-UHP eclogites in cold subduction zones may represent one of the largest, yet overlooked, sources of abiotic CH₄ on Earth.

SUBMITTER: Zhang L

PROVIDER: S-EPMC9840456 | biostudies-literature | 2023 Jan

REPOSITORIES: biostudies-literature

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Massive abiotic methane production in eclogite during cold subduction.

Zhang Lijuan L Zhang Lifei L Tang Ming M Wang Xiao X Tao Renbiao R Xu Cheng C Bader Thomas T

National science review 20220930 1

Methane (CH4) is a critical but overlooked component in the study of the deep carbon cycle. Abiotic CH4 produced by serpentinization of ultramafic rocks has received extensive attention, but its formation and flux in mafic rocks during subduction remain poorly understood. Here, we report massive CH4-rich fluid inclusions in well-zoned garnet from eclogites in Western Tianshan, China. Petrological characteristics and carbon-hydrogen isotopic compositions confirm t ...[more]

PMID: 36654916

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Project description:The Allalin gabbro of the Zermatt-Saas meta-ophiolite consists of variably metamorphosed Mg- to Fe-Ti-gabbros, troctolites, and anorthosites, which are crosscut by basaltic dykes. Field relationships of the various rock types and petrographic studies together with bulk rock and mineral chemical composition data allow the reconstruction of the complete geological history of the Allalin gabbro. With increasing magmatic differentiation, the incompatible element content in clinopyroxene increases (e.g., REEs and Zr by a factor of 5), whereas the Mg# decreases (from 86.4 to 74.6) as do the compatible element contents (e.g., Cr and Ni by factors of 3.5 and 5, respectively). Exhumation to shallower depths led to subsolidus ductile deformation and cooling of the gabbro followed by the intrusion of fine-grained basaltic dykes, which display chilled margins. Bulk rock data of these dykes reveal strong similarities in fluid-immobile trace element patterns to tholeiitic pillow basalts of the Zermatt-Saas and nearby meta-ophiolites. The recalculated REE patterns of the melt in equilibrium with igneous clinopyroxene is very similar to the REE patterns of the mafic dykes, indicating a cogenetic origin of pillow basalts, dykes, and gabbros. Together with the previously determined Jurassic intrusion age of the gabbro, our observations demonstrate that the Allalin gabbro intruded as a tholeiitic magma in a slow spreading MOR environment of the Piemonte-Ligurian ocean of the Alpine Tethys. Subduction of the Allalin gabbro resulted in different eclogitization extents of the Mg-gabbros as a function of variable hydration degrees. Metagabbros with low extents of hydration record incomplete eclogitization; the magmatic mineralogy (olivine + clinopyroxene + plagioclase) is preserved together with disequilibrium textures in the form of reaction coronae surrounding mineral boundaries. Metagabbros with high extents of hydration are completely eclogitized and display pseudomorphic replacement textures of magmatic minerals by eclogite-facies mineral assemblages, which required significant major to trace element transport across mineral domains. The locally variable extents of hydration took place near the sea floor, as recorded by the presence of Cl-apatite (6.28 wt% Cl), and an increase in B concentrations of minerals pseudomorphically replacing olivine (e.g., chlorite with 0.20-0.31 µg/g B and omphacite with 0.22-0.25 µg/g B) compared to magmatic olivine (0.12-0.16 µg/g B). Moreover, the chemical zonation pattern of metamorphic garnet coronae is different in completely eclogitized gabbros and gabbros with relic igneous minerals, in agreement with a main hydration event prior to subduction. The Allalin gabbro therefore represents a classical example of an oceanic gabbro formed in a slow spreading setting in the mid Jurassic that experienced heterogeneous hydration near the sea floor. Paleogene subduction of the gabbro to 70-80 km depth produced variably equilibrated gabbroic eclogites. In eclogite-facies Mg-gabbros, the water-rich minerals chlorite, talc, and chloritoid pseudomorphing magmatic olivine remained stable to these depths, revealing the potential relevance of hydrated Mg-gabbros as a fluid source at subarc depths in subduction zones.Supplementary informationThe online version contains supplementary material available at 10.1186/s00015-024-00461-8.

Dataset Information

Massive abiotic methane production in eclogite during cold subduction.

Publications

Massive abiotic methane production in eclogite during cold subduction.

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