Ultrasound enhanced solubilization of forest biorefinery hydrolysis lignin in mild alkaline conditions.

ABSTRACT: In the forest biorefinery, hydrolysis lignin (HL) is often dissolved with high concentration NaOH solution, followed by acid precipitation to obtain purified HL. For the first time, this study evaluates the effect of ultrasound (US) on the dissolution of industrially produced HL in aqueous NaOH solutions and the acid precipitation yield of HL. The solubility of HL in mild aqueous NaOH solutions was studied with and without US treatment at 20 kHz concerning the solid-to-liquid ratio, molecular weight of dissolved fractions and structural changes in dissolved HL. Results showed that the solubility of HL at 25 °C was strongly dependent on NaOH concentration. However, the US treatment significantly improved the solubility of HL, reaching a solubility plateau at 0.1 NaOH/HL ratio. US treatment

SUBMITTER: Puss KK 

PROVIDER: S-EPMC9841232 | biostudies-literature | 2023 Jan

REPOSITORIES: biostudies-literature