Solvent Tuning Excited State Structural Dynamics in a Novel Bianthryl.

ABSTRACT: Symmetry breaking charge separation (SBCS) is central to photochemical energy conversion. The widely studied 9,9-bianthryl (9,9'BA) is the prototype, but the role of bianthryl structure is hardly investigated. Here we investigate excited state structural dynamics in a bianthryl of reduced symmetry, 1,9-bianthryl (1,9'BA), through ultrafast electronic and vibrational spectroscopy. Resonance selective Raman in polar solvents reveals a Franck-Condon state mode that disappears concomitant with the rise of ring breathing modes of radical species. Solvent-dependent dynamics show that CS is driven by solvent orientational motion, as in 9,9'BA. In nonpolar solvents the excited state undergoes multistep structural relaxation, including subpicosecond Franck-Condon state decay and biexponential diffu

SUBMITTER: Roy P 

PROVIDER: S-EPMC9841557 | biostudies-literature | 2023 Jan

REPOSITORIES: biostudies-literature