X-ray absorption near edge structure spectroscopy reveals phosphate minerals at surface and agronomic sampling depths in agricultural Ultisols saturated with legacy phosphorus.

ABSTRACT: Legacy phosphorus (P) soils have received excessive P inputs from historic manure and fertilizer applications and present unique management challenges for protecting water quality as soil P saturation leads to increased soluble P to waterways. We used P K-edge X-ray absorption near edge structure (XANES) spectroscopy to identify and quantify the dominant P minerals in four representative legacy P soils under conventional till and no-till management in Maryland, USA. Various measures of extractable soil P, including water-extractable P (20.6-54.1 mg kg^-1 at 1:10 soil-to-water ratio; 52.7-132.2 mg kg^-1 at 1:100 soil-to-water ratio), plant available P extracted with Mehlich 3 (692-1139 mg kg^-1), and Mehlich 3P saturation ratio (0.54-1.37), were above the envir

SUBMITTER: Lucas E 

PROVIDER: S-EPMC9843306 | biostudies-literature | 2022 Dec

REPOSITORIES: biostudies-literature