Reconciling discrepant minor sulfur isotope records of the Great Oxidation Event.

ABSTRACT: Understanding the timing and trajectory of atmospheric oxygenation remains fundamental to deciphering its causes and consequences. Given its origin in oxygen-free photochemistry, mass-independent sulfur isotope fractionation (S-MIF) is widely accepted as a geochemical fingerprint of an anoxic atmosphere. Nevertheless, S-MIF recycling through oxidative sulfide weathering-commonly termed the crustal memory effect (CME)-potentially decouples the multiple sulfur isotope (MSI) record from coeval atmospheric chemistry. Herein, however, after accounting for unrecognised temporal and spatial biases within the Archaean-early-Palaeoproterozoic MSI record, we demonstrate that the global expression of the CME is barely resolvable; thereby validating S-MIF as a tracer of contemporaneous atmospheric che

SUBMITTER: Uveges BT 

PROVIDER: S-EPMC9845385 | biostudies-literature | 2023 Jan

REPOSITORIES: biostudies-literature