Selective and high-rate CO₂ electroreduction by metal-doped covalent triazine frameworks: a computational and experimental hybrid approach.

ABSTRACT: The electrochemical CO₂ reduction reaction (CO₂RR) has attracted intensive attention as a technology to achieve a carbon-neutral society. The use of gas diffusion electrodes (GDEs) enables the realization of high-rate CO₂RRs, which is one of the critical requirements for social implementation. Although both a high reaction rate and good selectivity are simultaneously required for electrocatalysts on GDEs, no systematic study of the relationship among active metal centers in electrocatalysts, reaction rate, and selectivity under high-rate CO₂RR conditions has been reported. In the present study, we employed various metal-doped covalent triazine frameworks (M-CTFs) as platforms for CO₂ reduction reaction (CO₂RR) electrocatalys

SUBMITTER: Kato S 

PROVIDER: S-EPMC9847663 | biostudies-literature | 2023 Jan

REPOSITORIES: biostudies-literature