Spontaneous Transition of Alkyl Carbocations to Unsaturated Vinyl-Type Carbocations in Organic Solutions.

ABSTRACT: It was found that alkyl carbocations, when their salts are dissolved in common organochlorine solvents, decompose to unsaturated vinyl-type carbocations that are stabler in solutions. This is a convenient method for obtaining salts of vinyl cations and their solutions for further research.

SUBMITTER: Stoyanov ES 

PROVIDER: S-EPMC9860910 | biostudies-literature | 2023 Jan

REPOSITORIES: biostudies-literature